Conductance of a molecular wire


Plenty of publications report on the conductance of molecular wires between electrodes. Characterization of the junction geometry, however, is usually missing. We synthesized a molecule for low-temperature STM experiments that stands vertically on a substrate. Despite this reductionist approach, its conductance data turned out to be
complex. Calculations show that geometrical changes, orbital symmetries, and bond formation control the conductance. This joint work within SFB677 by
Torben Jasper-Tönnies, Aran Garcia-Lekue, Thomas Frederiksen, Sandra Ulrich, Rainer Herges, and Richard Berndt has recently been published in Physical Review Letters and highlighted as Editors' Selection.