Physikalisches Kolloquium: Prof. D. C. Johnson (University of Oregon)

Materials by Design: Heterostructures with Targeted Nanoarchitecture and Tunable Properties

29.01.2019 ab 16:15

Leibnizstr. 13, 24118 Kiel, Hans-Geiger Hörsaal


We have shown that by controlling the local composition of an amorphous intermediate on the
nanoscale it is possible to kinetically control the self-assembly of new nanostructured compounds
consisting of two or more compounds with different crystal structures that are precisely interleaved
on the nanoscale. We have used this approach to synthesize hundreds of new metastable compounds
with designed nanostructure, including structural isomers. Many of these materials have
unprecedented physical properties, including the lowest thermal conductivities ever reported for a
fully dense solid, systematic structural changes dependent on nanostructure, and charge density
wave transitions. The designed precursors enable diffusion to be followed and quantified over
distances of less than a nanometer, providing insights to the mechanism that gives control of the
nanoarchitecture of the final product. We believe the ability to prepare entire families of new
nanostructured compounds and equilibrating them to control carrier concentrations permits a new
"thin film metallurgy" or “nanochemistry” in which nanostructure and composition can both be
used to tailor physical properties, interfacial structures can be determined for precisely defined
constituent thicknesses, and interfacial phenomena and modulation doping can be systematically

Diesen Termin meinem iCal-Kalender hinzufügen